Poisonarrow + apply poison
Apply poison can be found at the ascalon settlement North of lions arch.
The easiest way to find the person that gives the skill is to accept the quest from the merchant (in the tent area b4 the storage), that quest will send you right to the person that has apply poison.
Now for those wondering about poison arrow, heres some screenies. They should do all the talkin ;], Havent found barrage yet ;[.
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